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Class 2 (2nd Engineer) MEKM 📅 Feb 2025

Exam Question

Periodical Lubricating Oil Analysis. Its correct interpretation and corrective measures are of critical significance for the maintenance of marine machineries. With reference to the modern analysis techniques employed for the condition of L.O, discuss the following: (16)

(a) Elemental (Spectrometric) Analysis

(b) Fourier Transform Infrared (FTIR) Spectroscopy

(c) Particle Count

(d) Base Number Vs Acid Number (16)

Reference Answer

Modern Analysis Techniques for Lubricating Oil Condition Analysis
(a) Elemental (Spectrometric) Analysis
Elemental analysis is used to determine the concentrations of 15-25 different elements, ranging from wear metals and contamination to oil additives. This technique operates on the principle of Atomic Emission Spectroscopy (AES) .
In AES, individual atoms within a sample are excited using a high-energy source. These atoms absorb energy and transition to a higher electronic state. Due to quantum physics, excited atoms rapidly release this gained energy, primarily by emitting light. The frequency (and thus wavelength) of the emitted light is characteristic of the atom's electronic structure. By measuring the amount of light emitted at specific wavelengths for elements like Iron, Copper, Zinc, and Sodium, their concentrations can be determined. The unit of measurement is parts per million (PPM) .

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